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Conformation‐dependent response to the protonation of diphenanthrioctaphyrin(1.1.1.0.1.1.1.0): a route to pseudorotaxane‐like structures.
Autorzy
Rok wydania
2020
Czasopismo
Numer woluminu
26
Strony
8555-8566
DOI
10.1002/chem.202000940
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Diphenanthrioctaphyrin(1.1.1.0.1.1.1.0), an expanded carbaporphyrinoid incorporating two phenanthrenylene moieties, exists as two separate, yet interconvertible, locked stereoisomers. These species demonstrate complex dynamic behavior upon protonation, consisting in multiple conformational rearrangements and anion‐binding events. The formation of one of the final dicationic forms is accompanied by the inclusion of a complex anion(s) within the macrocyclic cavity yielding a pseudorotaxane‐like host–guest complex. Protonation with trifluoroacetic or dichloroacetic acids followed by neutralization afforded a conformation‐switching cycle, which involves six structurally different species. Analogous acidification with chiral 10‐camphorsulfonic acid and subsequent neutralization generated one of the free base stereoisomers with enantiomeric excess. Therefore, it was shown that the simple acid‐base chemistry of diphenanthrioctaphyrin can act as stimulus, inducing chirality into the system, allowing for the manipulation of the stereochemical information imprinted into the enantiomers of the macrocycle.
Słowa kluczowe
anion binding, chirality, conformational equilibria, porphyrinoids, pseudorotaxanes
Adres publiczny
http://dx.doi.org/10.1002/chem.202000940
Strona internetowa wydawcy
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